Dioxygen Activation: Modeling Copper Oxygenases and Oxidases news

Mechanisms for Hydrogen-Atom Abstraction by Mononuclear Copper(III) Cores: Hydrogen-Atom Transfer or Concerted Proton-Coupled Electron Transfer?

Mukunda Mandal, Courtney E. Elwell, Caitlin J. Bouchey, Timothy J. Zerk, William B. Tolman,* and Christopher J. Cramer* Journal of the American Chemical Society 2019, 141, 17236-17244 (DOI: 10.1021/jacs.9b08109).