Dioxygen Activation: Modeling Copper Oxygenases and Oxidases

Can an Ancillary Ligand Lead to a Thermodynamically Stable End-On 1:1 Cu-O2 Adduct Supported by a β-Diketiminate Ligand?

David E. Heppner, Benjamin F. Gherman, William B. Tolman, and Christopher J. Cramer, Dalton Trans. 2006, 4773 – 4782.

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